Worksheet 16 - Hybridization
When atoms bond to form molecules, they use molecular orbitals. These are
formed through the hybridization of the atomic orbitals that we have already
discussed, s, p, and d orbitals.
The hybridized molecular orbitals have different shapes and energy levels
than the atomic orbitals. The number of molecular orbitals created by
hybridization depends on the number of atomic orbitals that are mixed to form
them.
3
In forming sp
hybridized orbitals, four atomic orbitals are mixed, one s and three
p. The energy diagram for this process is shown below. The hybridized orbitals
are higher in energy than the s orbital, but lower in energy than the p orbitals,
following Hund's rule.
p
energy
3
sp
s
hybridization
atomic orbitals
hybridized orbitals
Carbon has 4 valence electrons. Add these electrons to the atomic and
molecular orbitals. This hybridization gives tetrahedral geometry.
With this hybridization, C will form four equivalent σ bonds.
3
Draw a similar energy diagram for sp
hybridized oxygen.
How many σ bonds will be formed?
3
How are the other sp
orbitals used?
3
Do the same for sp
hybridized nitrogen.