Naming Compounds
Naming compounds is an important part of chemistry. Most compounds fall in to one of
three categories- ionic compounds, molecular compounds, or acids.
Part One: Naming Ionic Compounds
Identifying Ionic Compounds
Ionic compounds consist of combinations of positively charged ions called cations (usually
metals), and negatively charged ions called anions (usually non-metals). In general, you can
identify an ionic compound because it contains a metal (these are usually found in the left
and center areas of the periodic table) and a non-metal (these are generally found in the right
hand area of the periodic table). Also, a compound will have no charge. For example, NaCl
and Fe
O
are ionic compounds; they each contain a metal (Na and Fe) and a non-metal (Cl
2
3
and O), and they do not have charges. MnO
-
is NOT an ionic compound; it does contain a
4
metal (Mn) and a non-metal (O), but it has a charge. Thus, it is a polyatomic ion, not a
compound. A compound will NEVER have a charge!
Naming Ionic Compounds
There are three steps involved in naming ionic compounds- naming the cation, naming the
anion, and naming the entire compound.
1. Name the cation.
i. Cations formed from metal atoms have the same name as the metal.
Examples: Na
+
= sodium ion; Al
3+
= aluminum ion
ii. If a metal can form ions of different charges (i.e., is one of the central
transition metals), specify the charge with Roman numerals in
parentheses. Examples: Fe
+
= iron (I) ion; Fe
2+
= iron (II) ion; Fe
3+
=
iron (III) ion
iii. Cations formed from nonmetal ions have names ending in –ium.
These are not common; the main ones are NH
+
(ammonium ion)
4
and H
O
+
(hydronium ion)
3
2. Name the anion.
i. Monoatomic anions (those formed from a single atom) have names
formed by replacing the end of the element name with –ide.
Examples: F
-
= fluoride ion; O
2-
= oxide ion. A few simple polyatomic
anions (those formed from multiples atoms) also have names ending
-
-
2-
in –ide. Examples: CN
= cyanide ion; OH
= hydroxide ion; O
=
2
peroxide ion.
ii. Most polyatomic ions contain oxygen, and have names ending in -
ate or -ite. They are known as oxyanions. The ending –ate is used for
the most common oxyanion form. The ending –ite is used for an
Naming Compounds
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Updated October 2013